Single-molecule magnet behaviour in polynuclear assembly of trivalent cerium ions with polyoxomolybdates.
نویسندگان
چکیده
An isopolyoxomolybdate-based POM is coordinated to trivalent cerium ions to afford a hybrid complex namely, [Ce(dmso)8][Ce(η2-NO3)2(dmso)4(α-Mo8O26)0.5][Mo6O19]. The original electrostatic environment created around the Ce(III) by its coordination to the isopolyoxomolybdate core induces complex single-molecule magnet behavior.
منابع مشابه
Correction: Single-molecule magnet behaviour in polynuclear assembly of trivalent cerium ions with polyoxomolybdates.
Correction for 'Single-molecule magnet behaviour in polynuclear assembly of trivalent cerium ions with polyoxomolybdates' by A. Ben Khélifa, et al., Dalton Trans., 2015, 44, 16458-16464.
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ورودعنوان ژورنال:
- Dalton transactions
دوره 44 37 شماره
صفحات -
تاریخ انتشار 2015